Pillararenes: Versatile Synthetic Receptors for Supramolecular Chemistry (Eur. J. Org. Chem. 15/2013)
Pillararenes: Versatile Synthetic Receptors for Supramolecular Chemistry (Eur. J. Org. Chem. 15/2013)
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DOI：
10.1002/ejoc.201390039
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发表时间：
2013-05
影响因子：
2.8
通讯作者：
Tomoki Ogoshi;T. Yamagishi
中科院分区：
文献类型：
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作者：
Tomoki Ogoshi;T. Yamagishi
2008年，我们报道了一类新的大环寄主，我们将其命名为“柱芳烃”。迄今为止，已经合成了分别含有5个和6个重复单元的[5]柱芳烃和[6]柱芳烃。柱状[5]芳烃和柱状[6]芳烃分别可容纳10个和12个取代基。这些取代基的位置选择性多功能功能化使各种超分子组装的制备成为可能。本文讨论了柱芳烃的合成及其选择性功能化。我们还讨论了各种柱芳烃衍生物作为超分子组件组件的使用，如传感器、自包合物、超分子二聚体、聚合物、柱芳烃和柱芳烃单元组成的交替聚合物、柱芳烃沿轴旋转的系统、轮烷、聚轮烷和柱芳烃基体材料，以及柱芳烃的胶体组件、生物医学应用和与无机材料的杂交。
In 2008 we reported a new class of macrocyclic hosts that we named “pillararenes”. To date, pillar[5]arenes and pillar[6]arenes, containing five and six repeating units, respectively, have been synthesized. Pillar[5]arenes and pillar[6]arenes can accommodate 10 and 12 substituent groups, respectively. The position-selective versatile functionalization of these substituents enables the preparation of various supramolecular assemblies. Here we discuss the synthesis and selective functionalization of pillararenes. We also discuss the use of the various pillararene derivatives as components of supramolecular assemblies such as sensors, a self-inclusion complex, supramolecular dimers, polymers, an alternating polymer consisting of pillar[5]arene and pillar[6]arene units, systems in which pillararene shuttles along an axle, rotaxanes, polyrotaxanes, and pillar[5]arene-based bulk-materials, as well as colloidal assembly of pillararenes, biomedical applications, and hybridization with inorganic materials.