A mechanistic study on the formation of silver nanoplates in the presence of silver seeds and citric acid or citrate ions.
A mechanistic study on the formation of silver nanoplates in the presence of silver seeds and citric acid or citrate ions.
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DOI：
10.1002/asia.201000728
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发表时间：
2011-02
期刊：
影响因子：
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通讯作者：
Jie Zeng;J. Tao;Weiyang Li;Jennifer Grant;P. Wang;Yimei Zhu;Younan Xia
中科院分区：
文献类型：
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作者：
Jie Zeng;J. Tao;Weiyang Li;Jennifer Grant;P. Wang;Yimei Zhu;Younan Xia
盘子里的世界：除了作为选择性结合银的{l_brace}111{r_brace}面的封端剂之外，羧酸根还可以与Ag+离子配位形成络合物，从而大大降低Ag+离子的还原率，从而形成具有孪晶面和堆垛层错的银晶种。
The world on a plate: In addition to their role as a capping agent that selectively binds to the {l_brace}111{r_brace} faces of silver, the carboxylate group can coordinate with Ag+ ions to form complexes and thus substantially reduce the reduction rate of Ag+ ions, leading to the formation of silver seeds with both twin planes and stacking faults.