The crystal morphology and mechanical properties based on poly(l-lactic acid)/silica nanocomposites

The crystal morphology and mechanical properties based on poly(l-lactic acid)/silica nanocomposites
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DOI:
10.1088/1757-899x/213/1/012034
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发表时间:
2017-06
期刊:
IOP Conference Series: Materials Science and Engineering
影响因子:
--
通讯作者:
Y. Cai
Y. Cai
中科院分区:
其他
文献类型:
--
作者:
Y. Cai

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将纳米二氧化硅(SiO2)引入聚L-乳酸(PLLA)基体中,制备了PLLA/SiO2纳米复合材料,并对其结晶形态、结晶行为和力学性能进行了研究。XRD测试结果表明,纳米SiO2对PLLA的结晶有促进作用,PLLA/SiO2纳米复合材料在等温结晶后出现尖锐的衍射峰。此外,通过POM分析,PLLA/SiO2样品具有典型的球晶结构,且球晶尺寸随着结晶温度的升高而变大。拉伸试验表明,少量SiO2的加入可以改善并保持PLLA的力学性能
Nano silica (SiO2) was introduced into Poly(L-lactic acid) (PLLA) matrix to prepare PLLA/SiO2 nanocomposites, and the crystal morphology, crystallization behavior and mechanical performance were investigated. The XRD experimental data indicated that nano SiO2 could improve the crystallization of PLLA, and PLLA/SiO2 nanocomposites exhibited sharp diffraction peak after isothermal crystallization. In addition, through the POM analysis, PLLA/SiO2 sample had the typical spherulite structure, and the size of the spherulite became larger with the increase of crystallization temperature. The tensile testing showed that a small amount of SiO2 could improve and retain the mechanical performance of PLLA