Dehydrogenation of ammonia-borane by Shvo's catalyst
Dehydrogenation of ammonia-borane by Shvo's catalyst
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DOI：
10.1039/c003157g
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发表时间：
2010-01-01
影响因子：
4.9
通讯作者：
Williams, Travis J.
中科院分区：
文献类型：
--
作者：
Conley, Brian L.;Williams, Travis J.
Shvo的环戊二烯酮连接钌配合物是一种有效的催化剂，可以从氨硼中释放出两摩尔当量的氢，氨硼是一种有前途的储氢介质。脱氢机理的特点是氢化钌的静息状态，其中二氢的损失是决定速率的步骤。
Shvo's cyclopentadienone-ligated ruthenium complex is an efficient catalyst for the liberation of exactly two molar equivalents of hydrogen from ammonia-borane, a prospective hydrogen storage medium. The mechanism for the dehydrogenation features a ruthenium hydride resting state from which dihydrogen loss is the rate-determining step.