THE TOTAL SYNTHESIS OF (+/-)-CIS-TRIKENTRIN-A AND (+/-)-TRANS-TRIKENTRIN-A
THE TOTAL SYNTHESIS OF (+/-)-CIS-TRIKENTRIN-A AND (+/-)-TRANS-TRIKENTRIN-A
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DOI：
10.1071/ch9900329
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发表时间：
1990-01-01
影响因子：
1.1
通讯作者：
MONAHAN, LC
中科院分区：
文献类型：
--
作者：
MACLEOD, JK;MONAHAN, LC
标题化合物是从海绵Trikentrion flabelliforme中分离得到的新型环戊二烯并[g]吲哚类化合物。氮烯的芳基环化和1，5-电环化反应是形成两个五元环的关键步骤。
The synthesis of the title compounds, which are novel cyclopent[g]indoles isolated from a marine sponge Trikentrion flabelliforme is described. An aryl radical cyclization and a 1,5-electrocyclic reaction of a nitrene are key steps on formation of the two five-membered rings.