Organic-functionalized, substituted polyoxovanadium and vanadoniobates: Synthesis, structure and application
Organic-functionalized, substituted polyoxovanadium and vanadoniobates: Synthesis, structure and application
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有机功能化、取代多氧钒和钒酸盐：合成、结构和应用
DOI：
10.1016/j.poly.2014.08.018
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发表时间：
2014
期刊：
影响因子：
2.6
通讯作者：
Hu Changwen
中科院分区：
文献类型：
--
作者：
Gao Yuanzhe;Chi Yingnan;Hu Changwen
多钒氧酸盐（Polyoxovanadates, pov）作为多金属氧酸盐（pom）的一个重要亚族，由于其丰富的结构化学和独特的性质，在催化、磁性、光学和医学等领域具有广泛的应用前景，一直受到人们的关注。在文献报道了大量异钒氧酸盐晶体结构的同时，杂原子掺入到多钒氧酸盐框架中用于功能材料也受到了相当大的关注。本文综述了近年来聚钒氧酸盐的研究进展，重点介绍了有机功能化、取代型聚钒氧酸盐和钒酸盐的研究进展。介绍了其合成方法、结构特点及其在催化和磁性方面的应用。讨论了这些新兴的多钒氧酸盐面临的挑战和前景。
Polyoxovanadates (POVs), as an important subfamily of polyoxometalates (POMs), have been attracting continuous interest due to their rich structural chemistry and unusual properties that make them attractive for applications in catalysis, magnetism, optics and medicine. In parallel with the large number of crystal structures of isopolyoxovanadates reported in the literature, the incorporation of heteroatoms into polyoxovanadate frameworks towards the functional materials has received considerable attention. This mini-review summarizes the recent advances on polyoxovanadates, and particularly highlights achievements that are concerned with organic-functionalized, substituted polyoxovanadium and vanadoniobates. We present the synthetic methods, structural features and applications mainly in catalysis and magnetism. The challenges and prospects of these emerging polyoxovanadates are also discussed.