The potential of methylsiloxanes as solvents for synthetic chemistry applications
The potential of methylsiloxanes as solvents for synthetic chemistry applications
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DOI：
10.1039/c3gc42036a
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发表时间：
2014-01-01
期刊：
影响因子：
9.8
通讯作者：
Xing, Jun-Yi
中科院分区：
文献类型：
--
作者：
Ab Rani, Mohd Azri;Borduas, Nadine;Xing, Jun-Yi
探讨了挥发性甲基硅氧烷（VMSs）作为化学品合成溶剂的潜在用途。这些VMS溶剂的环境影响的评估，发现是显着低于那些非极性有机溶剂，他们有可能取代。VMSs的极性，表示由经验极性测量，和与其他液体的亲油度被发现是类似的烷烃溶剂。最后，一些用途VMSs作为溶剂的有机和无机转换进行了说明。VMS为它们有可能取代的非极性溶剂提供了环境上更可持续（更绿色）的替代品。
The potential use of volatile methylsiloxanes (VMSs) as solvents for chemicals synthesis has been explored. Assessment of the environmental impact of these VMS solvents is made and found to be significantly lower than those of the non-polar organic solvents that they have the potential to replace. The polarities of the VMSs, as expressed by empirical polarity measurements, and miscibilities with other liquids are found to be similar to those of alkane solvents. Finally, some uses of VMSs as solvents for both organic and inorganic transformations are described. The VMSs provide environmentally more sustainable (greener) alternatives to the nonpolar solvents that they have the potential to replace.