Organocatalysis in the asymmetric synthesis of nitrogen-containing compounds: How and why
Organocatalysis in the asymmetric synthesis of nitrogen-containing compounds: How and why
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DOI：
10.2533/chimia.2007.224
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发表时间：
2007-01-01
期刊：
影响因子：
1.2
通讯作者：
Ricci, Alfredo
中科院分区：
文献类型：
--
作者：
Bernardi, Luca;Fini, Francesco;Ricci, Alfredo
在含氮化合物的不对称合成中，各种类型的多官能团化的立体定义的有机分子似乎是非常有用的有机催化剂。除了Aza-Henry、Friedel-Craft和Strecker等命名反应之外，使用合适的有机催化物种可以很容易地实现其他具有代表性的转化，如氢膦基化，在此报告中特别强调反应和立体化学结果以及机理见解。
Various types of polyfunctionalised stereodefined organic molecules appear to be highly serviceable as organocatalysts in the asymmetric synthesis of nitrogen-containing compounds. Beyond name reactions such as the aza-Henry, the Friedel-Crafts, and the Strecker other representative transformations like the hydrophosphonylation can be easily approached by using the suitable organocatalytic species and are herein reported with a special emphasis placed on the reaction and stereochernical outcomes and on the mechanistic insights.