Iron-catalyzed carbolithiation of alkynes having no heteroatoms.
Iron-catalyzed carbolithiation of alkynes having no heteroatoms.
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DOI：
10.1039/b900345b
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发表时间：
2009-04
影响因子：
4.9
通讯作者：
E. Shirakawa;D. Ikeda;Tsubasa Ozawa;S. Watanabe;Tamio Hayashi
中科院分区：
文献类型：
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作者：
E. Shirakawa;D. Ikeda;Tsubasa Ozawa;S. Watanabe;Tamio Hayashi
烷基和芳基锂化合物被发现在铁或铁-铜催化剂的存在下与不含杂原子的炔烃加成，得到各种三取代的乙烯基锂化合物。
Alkyl- and aryllithium compounds were found to add to alkynes having no heteroatoms in the presence of an iron or iron-copper catalyst to give various trisubstituted vinyllithium compounds.