SYNTHESIS AND RADICAL RING-OPENING POLYMERIZATION OF SPIRO O-CARBONATES
SYNTHESIS AND RADICAL RING-OPENING POLYMERIZATION OF SPIRO O-CARBONATES
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DOI：
10.1002/pol.1975.170131110
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发表时间：
1975-01-01
影响因子：
--
通讯作者：
BAILEY, WJ
中科院分区：
文献类型：
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作者：
ENDO, T;BAILEY, WJ
研究了螺环碳酸酯（I-IV）的合成和自由基开环聚合。 这些聚合物为黄色粉末，可溶于普通有机溶剂。红外光谱和核磁共振谱表明，聚合物是含双键的碳酸酯和碳酸酯的交替共聚物。讨论了聚合机理。
Syntheses and radical ring‐opening polymerization of spiroo‐carbonates(I‐IV) were investigated. These polymers were yellow powders and soluble in common organic solvents. The infrared and NMR spectra indicated that the polymers were alternate copolymers of either and carbonate containing double bonds. The polymerization mechanism is discussed.