Evidence for a reactive (alkene)peroxoiridium(III) intermediate in the oxidation of an alkene complex with O2.
Evidence for a reactive (alkene)peroxoiridium(III) intermediate in the oxidation of an alkene complex with O2.
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烯烃络合物与 O2 氧化过程中反应性（烯烃）过氧化铱（III）中间体的证据。
DOI：
10.1039/c2cc17332h
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发表时间：
2012
影响因子：
4.9
通讯作者：
J. Rohde
中科院分区：
文献类型：
--
作者：
M. R. Kelley;J. Rohde
一种（烯烃）过氧铱（III）配合物[Ir（L）（cod）（O（2））] [其中LH = PhN=C（NMe（2））NHPh，cod = 1，5-环辛烯]被鉴定为Ir（I）前体[Ir（L）（cod）]与O（2）反应的中间体，并通过光谱方法进行了表征。中间体衰变并进一步与1，5-环辛烯反应生成4-环辛烯-1-酮。
An (alkene)peroxoiridium(III) complex, [Ir(L)(cod)(O(2))] [where LH = PhN=C(NMe(2))NHPh and cod = 1,5-cyclooctadiene], was identified as an intermediate in the reaction of the Ir(I) precursor [Ir(L)(cod)] with O(2) and characterized by spectroscopic methods. Decay of the intermediate and further reaction with 1,5-cyclooctadiene produced 4-cycloocten-1-one.
影响因子：
4.6
作者：
Cornell, Candace N.;Sigman, Matthew S.
通讯作者：
Sigman, Matthew S.