1-Allyl-3-methylimidazolium chloride room temperature ionic liquid: A new and powerful nonderivatizing solvent for cellulose

1-Allyl-3-methylimidazolium chloride room temperature ionic liquid: A new and powerful nonderivatizing solvent for cellulose
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DOI:
10.1021/ma0505676
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发表时间:
2005-10-04
期刊:
影响因子:
5.5
通讯作者:
He, JS
He, JS
中科院分区:
化学1区
文献类型:
--
作者:
Zhang, H;Wu, J;He, JS

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一种新型高效直接溶剂- 1-烯丙基-3-甲基咪唑氯(AMIMCI)用于纤维素的溶解和再生。未经任何预处理的纤维素样品易于溶解在AMIMCI中。在水中混凝法制备的再生纤维素材料具有良好的力学性能。由于其耐热性和不挥发性,AMIMCI很容易回收。因此,本研究开发了一种利用AMIMCI生产再生纤维素材料的新型无污染工艺。
A new and highly efficient direct solvent, 1-allyl-3-methylimidazolium chloride (AMIMCI), has been used for the dissolution and regeneration of cellulose. The cellulose samples without any pretreatment were readily dissolved in AMIMCI. The regenerated cellulose materials prepared by coagulation in water exhibited a good mechanical property. Because of its thermostable and nonvolatile nature, AMIMCI was easily recycled. Therefore, a novel and nonpolluting process for the manufacture of regenerated cellulose materials using AMIMCI has been developed in this work.