A Series of [MnMo9O32]6– Based Solids: Homochiral Transferred from Adjacent Polyoxoanions to One-, Two-, and Three-Dimensional Frameworks
A Series of [MnMo9O32]6– Based Solids: Homochiral Transferred from Adjacent Polyoxoanions to One-, Two-, and Three-Dimensional Frameworks
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DOI：
10.1021/cg2004936
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发表时间：
2012-02
影响因子：
3.8
通讯作者：
H. Tan;Yang-guang Li;Wei-Lin Chen;A. Yan;Ding Liu;E. Wang
中科院分区：
文献类型：
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作者：
H. Tan;Yang-guang Li;Wei-Lin Chen;A. Yan;Ding Liu;E. Wang
合成了五个新的Waugh型多氧阴离子[MnMo9O32]6-Na4Mn[MnMo9O32]·11.5H2O(1)，KNa3Mn[MnMo9O32]·9H2O(2)，Na2Ni2[MnMo9O32]·12H2O(3)，L-Mn3[MnMo9O32]·13H2O(4a)，d-Mn3[MnMo9O32]·13H2O(4b)，L-Ni3[MnMo9O32]·11.5H2O(5a)。在这些化合物中，随着晶体中Na+/Tm(Tm=Mn2+，Ni2+)的变化，同手性相互作用分别从相邻的两个[MnMo9O32]6-体系扩展到一维体系(化合物1和2)、二维体系(化合物3)和三维体系(化合物4和5)。
Five new compounds based on the Waugh-type polyoxoanion [MnMo9O32]6– Na4Mn[MnMo9O32]·11.5H2O (1), KNa3Mn[MnMo9O32]·9H2O (2), Na2Ni2[MnMo9O32]·12H2O (3), l-Mn3[MnMo9O32]·13H2O (4a), d-Mn3[MnMo9O32]·13H2O (4b), and l-Ni3[MnMo9O32]·11.5H2O (5a) have been synthesized. In these compounds, with the changes of Na+/TM (TM = Mn2+, Ni2+) in the crystal, the homochiral interactions were extended from two adjacent [MnMo9O32]6– to one-dimensional (compounds 1 and 2), two-dimensional (compound 3), and three-dimensional (compounds 4 and 5) systems, respectively.