Stepwise assembly of two 3d-4d heterometallic coordination polymers based on a hexanuclear silver(I) metalloligand.
Stepwise assembly of two 3d-4d heterometallic coordination polymers based on a hexanuclear silver(I) metalloligand.
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DOI：
10.1039/c0cc03534c
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发表时间：
2011-01
影响因子：
4.9
通讯作者：
Di Sun;Dan-Feng Wang;Xi-Guang Han;N. Zhang;Rong-Bin Huang;Lan-Sun Zheng
中科院分区：
文献类型：
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作者：
Di Sun;Dan-Feng Wang;Xi-Guang Han;N. Zhang;Rong-Bin Huang;Lan-Sun Zheng
以六核银（I）配体为基础，通过三步合成法合成了两种新型的3d-4d异金属配位聚合物{[Cu（3）（bipy）（3）（H（2）O）（5）][Ag（6）（mna）（6）]·11.5H（2）O}（n）（1）和{[Zn（3）（eda）（3）（H（2）O）（4）][Ag（6）（mna）（6）]·8H（2）O}（n）（2（bipy = 2，2 ′-联吡啶，eda =乙二胺和H（2）mna = 2-巯基烟酸）。并讨论了化合物1和2的光致发光行为。
Two novel 3d-4d heterometallic coordination polymers {[Cu(3)(bipy)(3)(H(2)O)(5)][Ag(6)(mna)(6)]·11.5H(2)O}(n) (1) and {[Zn(3)(eda)(3)(H(2)O)(4)][Ag(6)(mna)(6)]·8H(2)O}(n) (2) were synthesized based on a hexanuclear silver(I) metalloligand by a three-step synthetic method (bipy = 2, 2'-bipyridine, eda = ethylenediamine and H(2)mna = 2-mercaptonicotinic acid). The photoluminescence behaviors of 1 and 2 were also discussed.