An XPS study of an isomorphous trivalent lanthanoid series
An XPS study of an isomorphous trivalent lanthanoid series
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DOI：
10.1016/s0368-2048(02)00011-7
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发表时间：
2002-06-01
影响因子：
1.9
通讯作者：
Wood, BJ
中科院分区：
文献类型：
--
作者：
Bernhardt, PV;Flanagan, BM;Wood, BJ
用X射线光电子能谱研究了一系列同构的稀土配合物[LnL(1)]中的核心电子结合能，其中Ln=La-Lu(Pm除外)，H3L是七齿配体2，2‘，2“-三(水杨酰亚胺)三乙胺。这项研究还研究了与该有机配体结合的三价稀土的自旋-轨道耦合，并解决了光谱中卫星峰的问题。(C)2002 Elsevier Science B.V.
X-ray photoelectron spectroscopy has been used to investigate the core electron binding energies within an isomorphous series of lanthanoid complexes; [LnL(1)] where Ln=La-Lu (except Pm) and H3L is the heptadentate ligand 2,2',2"-tris(salicylideneimino)triethylamine. This study also examines spin-orbit coupling of the trivalent lanthanoids bound to this organic ligand and addresses the issue of satellite peaks in the spectra. (C) 2002 Elsevier Science B.V. All rights reserved.