Sustainable and Efficient Low-Energy Light Emitters: A Series of One-Dimensional d10 Coinage Metal-Organic Chalcogenolates, [M(o-SPhCO2H)]n
Sustainable and Efficient Low-Energy Light Emitters: A Series of One-Dimensional d10 Coinage Metal-Organic Chalcogenolates, [M(o-SPhCO2H)]n
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DOI：
10.1002/cptc.202200030
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发表时间：
2022-03-04
期刊：
影响因子：
3.7
通讯作者：
Demessence, Aude
中科院分区：
文献类型：
--
作者：
Veselska, Oleksandra;Guillou, Nathalie;Demessence, Aude
报道了一系列d（10）钴硫代水杨酸金属配位聚合物（CPs）。Cu和Ag化合物的一维结构由M3S3稠合六边形组成，而Au化合物的一维结构由相互贯穿的螺旋链组成。根据不同的金属，固态红色和近红外发射CP的量子产率高达50%，提供了一个很好的机会，以取代实际的发射关键原材料。
A series of d(10) coinage metal thiosalicylate coordination polymers (CPs) is reported. The 1D structures of the three CPs are formed by M3S3 fused hexagons for Cu and Ag compounds and interpenetrated helical chains for Au CP. Depending on the metal, solid-state red and NIR emissive CPs are obtained with quantum yields up to 50 %, providing a great opportunity to replace the actual emissive critical raw materials.