Synthesis and methane-binding properties of disulfide-linked cryptophane-0.0.0.
Synthesis and methane-binding properties of disulfide-linked cryptophane-0.0.0.
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DOI：
10.1002/anie.201106512
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发表时间：
2012-01
影响因子：
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通讯作者：
M. A. Little;Jessica Donkin;J. Fisher;M. Halcrow;Jordan Loder;M. Hardie
中科院分区：
文献类型：
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作者：
M. A. Little;Jessica Donkin;J. Fisher;M. Halcrow;Jordan Loder;M. Hardie
进入地窖：环三噻吩直接偶联得到了一类新的具有不稳定二硫键的cryptophane，这是迄今报道的最小的cryptophane。新的隐石（见结构，S黄色，C灰色，H浅灰色）显示出在溶液中结合甲烷或氮。
Into the crypt: Direct coupling of cyclotrithiophenolene gives a new class of cryptophane with labile disulfide linkages, which is the smallest cryptophane yet reported. The new cryptophane (see structure, S yellow, C gray, H light gray) is shown to bind methane or nitrogen in solution.