The phosphaethynolate anion reacts with unsaturated bonds: DFT investigations into [2+2], [3+2] and [4+2] cycloadditions
The phosphaethynolate anion reacts with unsaturated bonds: DFT investigations into [2+2], [3+2] and [4+2] cycloadditions
复制标题
磷酸乙炔阴离子与不饱和键反应：[2 2]、[3 2] 和 [4 2] 环加成的 DFT 研究
DOI：
10.1039/c4cc04610b
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发表时间：
2014-01-01
影响因子：
4.9
通讯作者：
Zhao, Yufen
中科院分区：
文献类型：
--
作者：
Liu, Liu;Zhu, Jun;Zhao, Yufen
Density functional theory (DFT) calculations were carried out to investigate the [2+2], [3+2] and [4+2] cycloadditions of the phosphaethynolate anion (PCO-). The results reveal that the electronic properties of different unsaturated compounds play a crucial role in reactivity and regioselectivity.
