Dichlorodimethylhydantoin-KF as an efficient reagent for one pot synthesis of dialkylfluorophosphates from dialkylphosphites
Dichlorodimethylhydantoin-KF as an efficient reagent for one pot synthesis of dialkylfluorophosphates from dialkylphosphites
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DOI：
10.1016/j.jfluchem.2007.11.008
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发表时间：
2008-03-01
影响因子：
1.9
通讯作者：
Kaushik, M. P.
中科院分区：
文献类型：
--
作者：
Gupta, A. K.;Achuya, J.;Kaushik, M. P.
研究了有机-无机杂化试剂二氯二甲基海因- KF（DCDMH-KF）混合物作为一种有效的试剂，在室温和较短的反应时间内通过亲电-亲核复分解反应将亚磷酸二烷基酯直接转化为相应的氟磷酸二烷基酯。(c)2007 Elsevier B. V.保留所有权利。
Organic-inorganic hybrid reagent dichlorodimethylhydantoin - KF (DCDMH - KF) mixture was explored as an efficient reagent for the direct conversion of dialkylphosphites to their corresponding dialkylfluorophosphates at room temperature and in shorter reaction times through a facile electrophilic - nucleophilic metathesis. (c) 2007 Elsevier B.V. All rights reserved.