High-valent intermediates of heme proteins and model compounds.
High-valent intermediates of heme proteins and model compounds.
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血红素蛋白和模型化合物的高价中间体。
DOI：
10.1016/s1367-5931(01)00272-1
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发表时间：
2001
影响因子：
7.8
通讯作者：
Harris,DL
中科院分区：
文献类型：
--
作者：
Harris,DL
最近的计算和实验探测的高价血红素蛋白质和模型化合物的中间体揭示了丰富的光谱的化学行为，这是依赖于性质的近端配体，金属中心，远端和近端结合位点的环境，卟啉大环结构，以及随之而来的电子结构。这些研究的结果揭示了潜在的复杂性，一旦人们认识到这种中间体的“变色龙”样行为是由高价中间体环境决定的，就可以简单地理解这种复杂性。
Recent computational and experimental probes of high-valent intermediates in heme proteins and model compounds reveal a rich spectrum of chemical behavior that is dependent on the nature of the proximal ligand, metal center, distal- and proximal-binding site environment, porphyrin macrocycle architecture, and consequent electronic structure. The results of such studies reveal an underlying complexity, which is simply understood once one is cognizant of the ‘chameleon’-like behavior of such intermediates is determined by the high-valent intermediate environment.