B-H Activation at a Rhodium(I) Center: Isolation of a Bimetallic Complex Relevant to the Transition-Metal-Catalyzed Dehydrocoupling of Amine-Boranes
B-H Activation at a Rhodium(I) Center: Isolation of a Bimetallic Complex Relevant to the Transition-Metal-Catalyzed Dehydrocoupling of Amine-Boranes
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DOI：
10.1002/anie.200905185
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发表时间：
2010-01-01
影响因子：
16.6
通讯作者：
Weller, Andrew S.
中科院分区：
文献类型：
--
作者：
Chaplin, Adrian B.;Weller, Andrew S.
（图）分离出了一种与过渡金属催化的胺-硼烷脱氢偶联反应机理相关的配合物。该结构（见图）在同一分子内包含三种不同的胺-硼烷活化模式。© 2010 Wiley-VCH Verlag GmbH and Co. KGaA.
(Figure Presented) A bimetallic complex that is relevant to the mechanism of transition-metal-catalyzed amine-borane dehydrocoupling has been isolated. The structure (see picture) contains three different amine-borane activation modes within the same molecule. © 2010 Wiley-VCH Verlag GmbH and Co. KGaA.