An Exceptional 54-Fold Interpenetrated Coordination Polymer with 103-srs Network Topology
An Exceptional 54-Fold Interpenetrated Coordination Polymer with 103-srs Network Topology
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DOI：
10.1021/ja202303b
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发表时间：
2011-08-03
影响因子：
15
通讯作者：
Ma, Jian-Fang
中科院分区：
文献类型：
--
作者：
Wu, Hua;Yang, Jin;Ma, Jian-Fang
纠缠是配位聚合物框架最重要的特征之一，由于其美学和拓扑兴趣而引起了广泛的关注。在纠缠系统中，互穿框架代表了一个有趣的子集。然而，很少有材料具有非常高水平的互穿性。在这项工作中，水热合成了一种具有 10(3)-srs 拓扑结构的配位聚合物，该聚合物由星形三齿配体、三(4-咪唑基苯基)胺和 Ag-I 离子构建。它包含创纪录的 54 个互穿网络。
Entanglement is one of the most important features of coordination polymer frameworks and has attracted considerable attention due to its aesthetic and topological interest. Among entangled systems, interpenetrating frameworks represent an intriguing subset; however, there are few examples of materials containing very high levels of interpenetration. In this work a coordination polymer with 10(3)-srs topology, constructed from a star-like tridentate ligand, tri(4-imidazolylphenyl)amine, and Ag-I ions, has been hydrothermally synthesized. It contains a record 54 interpenetrating networks.