Microwave assisted co-precipitation synthesis and photoluminescence characterization of spherical Sr2P2O7:Ce3+, Tb3+ phosphors

Microwave assisted co-precipitation synthesis and photoluminescence characterization of spherical Sr2P2O7:Ce3+, Tb3+ phosphors
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球形Sr2P2O7:Ce3、Tb3荧光粉的微波辅助共沉淀合成及光致发光表征

DOI:
10.1016/j.jallcom.2013.06.085
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发表时间:
2013-12
影响因子:
6.2
通讯作者:
Jia, Dianzeng
Jia, Dianzeng
中科院分区:
材料科学2区
文献类型:
--
作者:
Xu, Mengjiao;Sheng, Rui;Liu, Lang;Jia, Dianzeng

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采用微波共沉淀法制备了一种新型球形绿色荧光粉Sr2P2O7:Ce3+,Tb3+。合成在1000 °C下进行15分钟。研究了样品的相结构、形貌、光致发光性能和热稳定性。在Tb 3+单掺Sr2P2O7荧光粉中共掺杂Ce 3+,由于Ce 3+向Tb 3+的能量传递,Tb 3+的绿色发光强度显著增强。该荧光粉具有良好的热稳定性和(0.258,0.605)的CIE色坐标,是一种潜在的绿色发光材料。微波辅助共沉淀法被认为是简单,快速和有利的,在实现所需的化学计量比和均匀性的前体材料相比,与传统的固态反应路线。
A novel spherical green phosphor, Sr2P2O7:Ce3+, Tb3+was prepared by co-precipitation method using a microwave heating system. The synthesis was performed at 1000 °C for 15 min. The phase structure, morphology, photoluminescence properties and thermal stability were investigated. The photoluminescence intensity of green emission from Tb3+was enhanced remarkably by co-doping Ce3+in the Tb3+solely doped Sr2P2O7phosphor because of energy transfer from Ce3+to Tb3+ions. The novel phosphors have excellent thermal stability and remarkable CIE chromaticity coordinates of (0.258, 0.605), indicating its potential application of green emitting phosphor in lighting field. The microwave-assisted co-precipitation method was found to be simple, rapid and advantageous in achieving the required stoichiometry and homogeneity of precursor materials in comparison with the conventional solid state reaction route.
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