Selectivity and Mechanism of Iridium-Catalyzed Cyclohexyl Methyl Ether Cleavage
Selectivity and Mechanism of Iridium-Catalyzed Cyclohexyl Methyl Ether Cleavage
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DOI:
10.1021/acscatal.0c01718
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发表时间:
2020-05
期刊:
影响因子:
12.9
通讯作者:
Caleb D. Fast;Caleb A. H. Jones;N. Schley
中科院分区:
文献类型:
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作者:
Caleb D. Fast;Caleb A. H. Jones;N. Schley
Cationic bis(phosphine)iridium complexes are found to catalyze the cleavage of cyclohexyl methyl ethers by triethylsilane. Selectivity for C−O cleavage is determined by the relative rates of SN2 de...