Selectivity and Mechanism of Iridium-Catalyzed Cyclohexyl Methyl Ether Cleavage

Selectivity and Mechanism of Iridium-Catalyzed Cyclohexyl Methyl Ether Cleavage
复制标题

DOI:
10.1021/acscatal.0c01718
复制
发表时间:
2020-05
期刊:
影响因子:
12.9
通讯作者:
Caleb D. Fast;Caleb A. H. Jones;N. Schley
Caleb D. Fast;Caleb A. H. Jones;N. Schley
中科院分区:
化学1区
文献类型:
--
作者:
Caleb D. Fast;Caleb A. H. Jones;N. Schley

文献摘要

相似文献

发现阳离子双(膦)铱配合物催化三乙基硅烷裂解环己基甲基醚。C−O裂解的选择性由SN2分解的相对速率决定。
Cationic bis(phosphine)iridium complexes are found to catalyze the cleavage of cyclohexyl methyl ethers by triethylsilane. Selectivity for C−O cleavage is determined by the relative rates of SN2 de...