Electrochemical studies of some conducting polythiophene films
Electrochemical studies of some conducting polythiophene films
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DOI：
10.1021/j100231a035
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发表时间：
1983-04
期刊：
影响因子：
--
通讯作者：
R. Waltman;J. Bargon;A. F. Diaz
中科院分区：
文献类型：
--
作者：
R. Waltman;J. Bargon;A. F. Diaz
聚噻吩和..贝塔.. -取代的聚噻吩通过它们各自的单体的电化学氧化和聚合来制备。通过单体化学结构的系统变化，得到单体及其相应聚合物之间的性能-结构相关性。薄膜生长和电导率取决于..贝塔.. -取代基，具有对于聚（...贝塔.. -甲基噻吩）。
Polythiophene and ..beta..-substituted polythiophenes are prepared by electrochemical oxidation and polymerization of their respective monomers. A property-structure correlation between monomers and their corresponding polymers is obtained by systematic variation of the chemical structure of the monomers. Film growth and conductivities are dependent on ..beta..-substituents, with conductivity of the order of 1 ohm/sup -1/ cm/sup -1/ obtained for poly(..beta..-methylthiophene).