Structural and Aromaticity Control of [34]Octaphyrin(1.1.1.0.1.1.1.0) by Protonation and Deprotonation
Structural and Aromaticity Control of [34]Octaphyrin(1.1.1.0.1.1.1.0) by Protonation and Deprotonation
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通过质子化和去质子化控制[34]八菲林(1.1.1.0.1.1.1.0)的结构和芳香度
DOI：
10.1002/ajoc.201700144
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发表时间：
2017
影响因子：
2.7
通讯作者：
Atsuhiro Osuka
中科院分区：
文献类型：
--
作者：
Koji Naoda;Atsuhiro Osuka
The structural and aromaticity control of hexakis(pentafluorophenyl) [34]octaphyrin(1.1.1.0.1.1.1.0)1was examined by protonation and deprotonation. Protonation of1with methanesulfonic acid (MSA) induced a structural change from a figure‐eight to a rectangular shape, accompanied by an aromaticity change from nonaromatic to strong Hückel aromatic. Deprotonation of1with tetrabutylammonium difluorotriphenylsilicate (TBAT) or fluoride (TBAF) produced a mono‐deprotonated species with a similar figure‐eight conformation and nonaromaticity.
