An efficient two-step synthesis of metal-free phthalocyanines using a Zn(II) template
An efficient two-step synthesis of metal-free phthalocyanines using a Zn(II) template
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DOI：
10.1039/b822985f
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发表时间：
2009-01-01
影响因子：
4.9
通讯作者：
Luedtke, Nathan W.
中科院分区：
文献类型：
--
作者：
Alzeer, Jawad;Roth, Phillipe J. C.;Luedtke, Nathan W.
在120℃的吡啶 - 盐酸体系中合成了一类含有四个胍基的新型阳离子酞菁；在这些条件下，锌从起始原料和产物中被去除，从而揭示了一种合成无金属酞菁的新途径。
A new family of cationic phthalocyanines containing four guanidinium groups was synthesized in pyridine-HCl at 120 degrees C; under these conditions zinc was removed from both the starting materials and products to reveal a new synthetic route to metal-free phthalocyanines.