Controlled Synthesis of Nanoscopic Metal Cages.
Controlled Synthesis of Nanoscopic Metal Cages.
复制标题
DOI：
10.1021/jacs.5b04664
复制
发表时间：
2015-06
影响因子：
15
通讯作者：
J. Ferrando‐Soria;Antonio Fernandez;Eufemio Moreno Pineda;Sarah A Varey;R. W. Adams;I. Vitorica-Yrezabal;F. Tuna;G. Timco;C. Muryn;R. Winpenny
中科院分区：
文献类型：
--
作者：
J. Ferrando‐Soria;Antonio Fernandez;Eufemio Moreno Pineda;Sarah A Varey;R. W. Adams;I. Vitorica-Yrezabal;F. Tuna;G. Timco;C. Muryn;R. Winpenny
在这里，我们展示了一个优雅的和一般的路线组装的巨大的{M12 C24}笼从12个钯离子（M）和24个异金属八核配位笼（C = {Cr 7 Ni-Py 2}）。该分子的大小为8 nm，其合成和表征方法为未来在此规模上的发展提供了基础。
Here we show an elegant and general route to the assembly of a giant {M12C24} cage from 12 palladium ions (M) and 24 heterometallic octanuclear coordination cages (C = {Cr7Ni-Py2}). The molecule is 8 nm in size, and the methods for its synthesis and characterization provide a basis for future developments at this scale.