Structural Characterization of Molybdenum-Dinitrogen Complex as Key Species toward Ammonia Formation by Dispersive XAFS Spectroscopy
Structural Characterization of Molybdenum-Dinitrogen Complex as Key Species toward Ammonia Formation by Dispersive XAFS Spectroscopy
复制标题
通过色散 XAFS 光谱法对作为氨形成关键物质的钼-二氮配合物进行结构表征
DOI：
10.1039/c9cp06761b
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发表时间：
2020
期刊：
影响因子：
--
通讯作者：
Hisao Yoshida
中科院分区：
文献类型：
--
作者：
Akira Yamamoto;Kazuya Arashiba;Shimpei Naniwa;Kazuo Kato;Hiromasa Tanaka;Kazunari Yoshizawa;Yoshiaki Nishibayashi;Hisao Yoshida
使用分散XAFS对带有PNP型钳配体的难分离钼-二氮配合物进行了结构表征，该配合物被认为是三碘化钼配合物[MoI3(PNP)]在二氮大气压下化学计量转化成相应氮化钼配合物时的关键反应配合物。
The structural characterization of a hardly-isolatable molybdenum–dinitrogen complex bearing a PNP-type pincer ligand, which is assumed to be a key reactive complex in the stoichiometric transformation of a molybdenum triiodide complex [MoI3(PNP)] into the corresponding molybdenum nitride complex under an atmospheric pressure of dinitrogen, was carried out by using dispersive XAFS.