Electric-field induced phase transition in a near-surface layer of a PbMg0.33Nb0.67O3-28% PbTiO3 (001) single-crystalline plate

Electric-field induced phase transition in a near-surface layer of a PbMg0.33Nb0.67O3-28% PbTiO3 (001) single-crystalline plate
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电场%20感应%20相%20转变%20in%20a%20近表面%20层%20of%20a%20PbMg0.33Nb0.67O3-28%%20PbTiO3%20(001)%20单晶%20板

DOI:
10.3139/146.101521
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发表时间:
2007
影响因子:
0.8
通讯作者:
D. Meyer
D. Meyer
中科院分区:
材料科学4区
文献类型:
--
作者:
A. Levin;A. I. Pommrich;T. Weissbach;P. Paufler;D. Meyer

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摘要利用广角x射线散射技术,在沿晶片[001]方向外加电场(场强E达13 kV cm−1)的影响下,对PbMg1/3Nb2/3O3-28 mol.% PbTiO3固化液(001)单晶片进行了室温原位研究。结构变化归因于铁电修饰之间的可逆相变的固溶体在近电极区域约1mm深。近电极层的一部分(在E = 4.5 kV cm - 1时约占5vol .%,在13 kV cm - 1时约占15vol .%)从最初的菱形结构转变为另一种结构,很可能是单斜相Mb相。x射线摇摆曲线轮廓形状的变化提示了电场诱导相变在自适应x射线光学中的可能技术应用。
Abstract An (001) single-crystal plate of a solid solution of PbMg1/3Nb2/3O3-28 mol.% PbTiO3 was investigated by Wide-Angle X-ray Scattering techniques at room temperature in situ under the influence of an external static electric field (field strength E up to 13 kV cm−1) applied along the [001] direction of the wafer. Structural changes attributed to a reversible phase transition between ferroelectric modifications of the solid solution in a near electrode region of about 1 mm depth are found. Part of the near-electrode layer (of about 5 vol.% at E = 4.5 kV cm−1 and about 15 vol.% at 13 kV cm−1) transforms from the initial rhombohedral structure to another one, most probably, the monoclinic Mb phase. Changes of the profile shape of X-ray rocking curves suggest possible technical use of the electric-field induced phase transition for adaptive X-ray optics.
通过外部电场可逆调谐 (001) SrTiO3 单晶板中 RuddlesdenâPopper 型 SrO(SrTiO3)n 的一系列共生相及其在自适应 X 射线光学中的潜在用途
DOI: 10.1007/s00339-006-3584-2
发表时间: 2006
期刊: Applied Physics A
影响因子: --
作者:
D.C. Meyer;A.A. Levin;T. Leisegang;E. Gutmann;P. Paufler;M. Reibold;H. Lichte;W. Pompe
通讯作者: W. Pompe