Swelling and elasticity of hydrogels based on poly(ethylene oxide) macroinimer

Swelling and elasticity of hydrogels based on poly(ethylene oxide) macroinimer
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DOI:
10.1002/pi.1334
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发表时间:
2004-03
影响因子:
3.2
通讯作者:
Demet Melekaslan;Fatmanur Kasapoglu;Koichi Ito;Y. Yagcı;O. Okay
Demet Melekaslan;Fatmanur Kasapoglu;Koichi Ito;Y. Yagcı;O. Okay
中科院分区:
化学3区
文献类型:
--
作者:
Demet Melekaslan;Fatmanur Kasapoglu;Koichi Ito;Y. Yagcı;O. Okay

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提出了一种制备聚环氧乙烷(PEO)水凝胶的新方法。同时具有可聚合中心和自由基生成中心的PEO大分子用于获得具有悬挂的PEO链的水凝胶。结果表明,PEO大分子单体在光聚合过程中既作为单体又作为交联剂,形成具有不同溶胀能力和弹性模数的水凝胶。2004年化学工业学会
A novel method for the preparation of hydrogels based on poly(ethylene oxide) (PEO) is presented. A PEO macroinimer possessing both polymerizable and radical generation sites was used to obtain hydrogels having dangling PEO chains. It was shown that PEO macroinimer acts during photopolymerization, both as a monomer and a crosslinker and thus, leads to the formation of hydrogels of various swelling capacities and moduli of elasticity.  2004 Society of Chemical Industry