Polyslipping: A New Approach to Polyrotaxane-like Assemblies
Polyslipping: A New Approach to Polyrotaxane-like Assemblies
复制标题
聚滑移：类聚轮烷组装的新方法
DOI：
10.1246/cl.2001.774
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发表时间：
2001
影响因子：
1.6
通讯作者：
T. Takata
中科院分区：
文献类型：
--
作者：
Yow;H. Fujimori;Junko Shoji;Yoshio Furusho;N. Kihara;T. Takata
双铵盐1和双冠醚5在丙酮或乙腈中的“多滑移”，即哑铃组分多次滑移成具有适当尺寸互补性的大环组分，得到聚轮烷样组装体6，其通过溶解在DMSO中定量地恢复为单体1和5。
“Polyslipping”, that is, multiple slipping of dumbbell components into macrocyclic ones having the appropriate size complementarity, of bis-ammonium salt 1 and bis-crown ether 5 in acetone or acetonitrile afforded polyrotaxane-like assembly 6, which quantitatively reverted to the monomers 1 and 5 by dissolving in DMSO.