Investigation of gold fluorides and noble gas complexes by matrix-isolation spectroscopy and quantum-chemical calculations.
Investigation of gold fluorides and noble gas complexes by matrix-isolation spectroscopy and quantum-chemical calculations.
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DOI：
10.1002/anie.201205072
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发表时间：
2012-10
影响因子：
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通讯作者：
Xuefeng Wang;L. Andrews;K. Willmann;Felix Brosi;S. Riedel
中科院分区：
文献类型：
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作者：
Xuefeng Wang;L. Andrews;K. Willmann;Felix Brosi;S. Riedel
高贵与不同：基质隔离实验和量子化学计算导致了两种新化合物的表征，即第一种开壳二元氟化金AuF（2）和NeAuF络合物。此外，ArAuF，AuF（3），Au（2）F（6）和单体AuF（5）已在低温条件下在氖和氩基质中产生和鉴定。
Noble with a difference: Matrix-isolation experiments and quantum-chemical calculations have led to the characterization of two new compounds, namely first open-shell binary gold fluoride, AuF(2), and a NeAuF complex. Moreover, ArAuF, AuF(3), Au(2)F(6), and monomeric AuF(5) have been produced and identified under cryogenic conditions in neon and argon matrices.