High ambipolar mobility in a highly ordered smectic phase of a dialkylphenylterthiophene derivative that can be applied to solution-processed organic field-effect transistors

High ambipolar mobility in a highly ordered smectic phase of a dialkylphenylterthiophene derivative that can be applied to solution-processed organic field-effect transistors
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DOI:
10.1002/adma.200602319
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发表时间:
2007-02-05
期刊:
影响因子:
29.4
通讯作者:
Tamaoki, Nobuyuki
Tamaoki, Nobuyuki
中科院分区:
材料科学1区
文献类型:
--
作者:
Funahashi, Masahiro;Zhang, Fapei;Tamaoki, Nobuyuki

文献摘要

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合成了一种在室温附近具有高度有序近晶相的苯基三噻吩衍生物。在近晶相的主体中,观察到双极载流子输运,并且电子迁移率超过0.2 cm(2)V-1 S-1。薄膜晶体管(参见图中的AFM图像)通过旋涂方法制造,并且表现出p型操作、0.02 cm(2)v(-1)s(-1)的场效应迁移率和10(6)的开/关比。
A phenylterthiophene derivative that exhibits a highly ordered smectic phase around room temperature is synthesized. In the bulk of the smectic phase, ambipolar carrier transport is observed and electron mobility exceeds 0.2 cm(2) V-1 S-1. Thin-film transistors (see the AFM image in the figure) are fabricated by a spin-coating method and exhibit p-type operation, a field-effect mobility of 0.02 cm(2) v(-1) s(-1), and an on/off ratio of 10(6).