Molecular construction based on icosahedral carboranes and aromatic N,N′-dimethylurea groups.: Aromatic layered molecules and a transition metal complex
Molecular construction based on icosahedral carboranes and aromatic N,N′-dimethylurea groups.: Aromatic layered molecules and a transition metal complex
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DOI：
10.1016/s0022-328x(02)01322-0
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发表时间：
2002-09-01
影响因子：
2.3
通讯作者：
Yamaguchi, K
中科院分区：
文献类型：
--
作者：
Endo, Y;Songkram, C;Yamaguchi, K
N-甲基芳香脲的顺式偏好与邻碳硼烷笼上C-取代基的调节相结合，适用于构建结构独特的大分子。合成了具有多层结构的芳香脲(5-12)和含有分子内硝基碳硼烷-钴络合物的芳香脲(13)，并通过X射线晶体学确定了它们的结构。 (C) 2002 Elsevier Science B.V. 保留所有权利。
cis-Preference of N-methyl aromatic ureas in combination with regulation of the C-substituent on an o-carborane cage is applicable to construct structurally unique macromolecules. Aromatic ureas with multilayer structure (5-12) and an aromatic urea containing an intramolecular nido-carborane-cobalt complex (13) were synthesized and their structures were determined by X-ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.