Asymmetric olefin aziridination using a newly designed Ru(CO)(salen) complex as the catalyst
Asymmetric olefin aziridination using a newly designed Ru(CO)(salen) complex as the catalyst
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DOI：
10.1039/c2cc32997b
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发表时间：
2012-01-01
影响因子：
4.9
通讯作者：
Katsuki, Tsutomu
中科院分区：
文献类型：
--
作者：
Kim, Chungsik;Uchida, Tatsuya;Katsuki, Tsutomu
以一种新设计的Ru(CO)(Salen)络合物为催化剂，在温和的条件下，实现了共轭和非共轭末端烯烃和环烯烃的高对映选择性和高产率的氮杂环化反应。
Highly enantioselective and good to high-yielding aziridination of conjugated and non-conjugated terminal olefins and cyclic olefins was achieved using a newly designed Ru(CO)(salen) complex as the catalyst in the presence of SESN3 under mild conditions.