Stable Isotope Geochemistry
Stable Isotope Geochemistry
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DOI：
10.1007/978-3-319-78527-1
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发表时间：
1973
期刊：
影响因子：
--
通讯作者：
J. Hoefs
中科院分区：
文献类型：
--
作者：
J. Hoefs
《稳定同位素地球化学》的九个版本在近50年的时间跨度内出版。第一版(1973年)只是一本135页的薄薄的书。由于该领域的快速发展，有时需要延长版本。前4个版本以经典的光元素，即所谓的Chons为中心。从2004年第5版开始--随着多收集器--电感耦合等离子体质谱--的引入，该书不得不扩大，因为更多的元素--第9版中的47种元素--可以以必要的高精度进行测量。元素数量的增加，加上使用从头算方法计算平衡同位素分馏的进展，导致出版物的数量令人难以置信地增加，再次需要进行重大修订和扩充。为了遵循国际理论和应用化学联合会(IUPAC)的建议，在新版中，DD一词已被D2H取代。这本书的大体结构保持不变。第一章介绍了本文的理论和实验原理。第二章分为两部分：第一部分讨论了气源质谱仪测定的“传统”元素氢、碳、氧、氮、硫。第二部分介绍了主要通过多收集器电感耦合质谱仪测量的“非传统同位素”。在一些地方，先后讨论了具有密切地球化学关系的元素。第二章概述了47种元素的天然同位素变化；在新版中增加了Rb、Zr、Nd、Eu和HREE。特别强调了过去三年发表的研究，同时仍总结了在此之前所作的重要发现。与以前的版本一样，第三部分在经典的地球化学“球体”的背景下讨论了同位素组成的自然变化。新增了陨石-地球关系、月球上的挥发性元素、岩浆岩中的镁和铁关系、俯冲带变质作用、矿床和海洋中的金属同位素变化以及碳同位素地层学。第三章以两个新的副标题结束：(I)法医同位素地球化学和(Ii)医学调查。一份带有许多新引用的非常长的参考文献列表使人们能够快速访问最近呈指数级增长的v
The nine editions of Stable Isotope Geochemistry have appeared over a time span of nearly 50 years. The first edition (1973) appeared as a slim book of 135 pages. Due to the rapid development of the field, extended editions became necessary from time to time. The first 4 editions centered on the classical light elements, so-called CHONS. From the 5th edition 2004—with the introduction of the Multicollector-ICP-Mass Spectrometry—the book had to be enlarged, because many more elements—47 elements in the 9th edition—can be measured with the necessary high precision. The increase of the number of elements, together with advances in the calculation of equilibrium isotope fractionation using ab initio methods, has led to an unbelievable rise of publications, making again a rewriting with substantial major revisions and extensions necessary. To follow the recommendations of the International Union of Pure and Applied Chemistry (IUPAC), the term dD has been replaced by d2H in the new edition. The general structure of the book has been kept. Chapter 1 gives a general introduction to the theoretical and experimental principles. Chapter 2 is divided in two parts: Part I discusses the “traditional” elements hydrogen, carbon, oxygen, nitrogen, and sulfur measured by gas-source mass-spectrometry. Part II presents the “non-traditional isotopes”, measured predominantly by multi-collector inductively coupled mass-spectrometry. At places elements with close geochemical relationships are discussed successively. Chapter 2 gives an overview of natural isotope variations of 47 elements; Rb, Zr, and Nd, Eu and the HREE have been added in the new edition. Special emphasis has been given to studies that have been published over the last three years, while still summarizing the important discoveries made before that time. As in earlier editions, the third part discusses natural variations of isotope compositions in the context of the classic geochemical “spheres”. New subsections have been added such as: Meteorite-Earth relationships, volatile elements on the Moon, magnesium and iron relationships in magmatic rocks, subduction-zone metamorphism, metal isotope variations in ore deposits and in the ocean, and carbon isotope stratigraphy. Chapter 3 ends with two new subtitles:(i) forensic isotope geochemistry and (ii) medical investigations. A very long list of references with many new citations enables a quick access to the exponentially growing recent v