Evaluation of the standard enthalpies and isobaric potentials of the formation of certain complex hydrides

Evaluation of the standard enthalpies and isobaric potentials of the formation of certain complex hydrides
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某些复合氢化物形成的标准焓和等压势的评估

DOI:
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发表时间:
1971
期刊:
影响因子:
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通讯作者:
T. Dymova
T. Dymova
中科院分区:
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文献类型:
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作者:
V. А. Kuznetsov;T. Dymova

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1. 采用比较计算的方法评价了碱土金属和氢化铝的氢化铝和硼氢化物的标准生成热和自由能。 2. 计算了硼氢化物和氢化铝分解成组分氢化物的热量和自由能。 3. 计算了第二组硼氢化物和氢化铝的分解热和自由能。 4. 在这两种类型的分解中,硼氢化物比相应的氢化铝更稳定。
1. The standard heats and free energies of formation of aluminum hydrides and borohydrides of the alkaline earth metals and aluminum hydride were evaluated by the method of comparative calculation. 2. The heats and free energies of the decomposition of borohydrides and aluminum hydrides into the component hydrides were calculated. 3. The heats and free energies of the decomposition of borohydrides and aluminum hydrides of the second group were calculated. 4. In both types of decomposition, borohydrides are more stable than the corresponding aluminum hydrides.