Palladium-catalyzed direct arylation of cyclic enamides with aryl silanes by sp(2) C-H activation.
Palladium-catalyzed direct arylation of cyclic enamides with aryl silanes by sp(2) C-H activation.
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DOI：
10.1002/anie.200901884
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发表时间：
2009-07
影响因子：
--
通讯作者：
Hai‐Feng Zhou;Yun‐He Xu;W. Chung;T. Loh
中科院分区：
文献类型：
--
作者：
Hai‐Feng Zhou;Yun‐He Xu;W. Chung;T. Loh
它真的进去了！通过钯催化的C-H活化，环烯酰胺与三烷氧基芳基硅烷的氟化物辅助的直接交叉偶联以高达95%的产率产生宽范围的烯酰胺。
It does get in! A fluoride-assisted direct cross-coupling of cyclic enamides with trialkoxy aryl silanes by a palladium-catalyzed C--H activation leads to a wide range of enamides in yields of up to 95 %.