Electro-reductive Halogen-Deuterium Exchange and Methylation of Aryl Halides in Acetonitrile

Electro-reductive Halogen-Deuterium Exchange and Methylation of Aryl Halides in Acetonitrile
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DOI：
10.5796/electrochemistry.81.362
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发表时间：
2013-05-01
期刊：
ELECTROCHEMISTRY
影响因子：
2.5
通讯作者：
Suga, Seiji
Suga, Seiji
中科院分区：
工程技术4区
文献类型：
--
作者：
Mitsudo, Koichi;Okada, Takahiro;Suga, Seiji

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本文报道了在CD_3CN中进行的电还原卤素-氘交换反应。以9-芴酮为介体，几种卤代芳烃的电还原反应顺利进行，选择性地得到氘代产物。芳基卤化物的甲基化反应也在类似条件下进行。(C)日本电化学学会，版权所有。
An electro-reductive halogen-deuterium exchange reaction in CD3CN has been developed. Using 9-fluorenone as a mediator, the electro-reduction of several aryl halides proceeded smoothly to give the deuterated products selectively. A methylation reaction of aryl halides also proceeded under similar conditions. (C) The Electrochemical Society of Japan, All rights reserved.