SURFACE-PLASMON POLARITON ENHANCEMENT OF RAMAN-SCATTERING IN KRETSCHMANN GEOMETRY
SURFACE-PLASMON POLARITON ENHANCEMENT OF RAMAN-SCATTERING IN KRETSCHMANN GEOMETRY
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DOI：
10.1021/j100330a009
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发表时间：
1988-09-22
影响因子：
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通讯作者：
USHIODA, S
中科院分区：
文献类型：
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作者：
GIERGIEL, J;REED, CE;USHIODA, S
结论过氧亚硝酸盐和氯过氧亚硝酸盐是反应1和反应2中相对不重要的副产物通道，因此在平流层化学中可能不重要。没有令人信服的证据（理论或实验）支持任何硝酸氯异构体的存在，尽管这项工作的理论结果表明过氧亚硝酸可能作为反应1的次要副产物存在于气相中。等待着实验验证，希望能得到本文提出的理论红外光谱的帮助。
ConclusionPeroxynitrous acid and chlorine peroxynitrite appear to be relatively unimportant byproduct channels for reactions 1 and 2 and, therefore, are not likely to be significant in stratospheric chemistry. No compelling evidence (theoretical or experimental) exists supporting the existence of any chlorine nitrate isomer, although the theoretical results of this work suggest peroxynitrous acid may exist in the gas phase as a minor byproduct of reaction 1. Experimental verification awaits, hopefully aided by the theoretical infrared spectrum presented herein.