Silver-copper co-catalyzed cascade intramolecular cyclization/desulfinamide/dehydrogenation: one-pot synthesis of substituted carbazoles
Silver-copper co-catalyzed cascade intramolecular cyclization/desulfinamide/dehydrogenation: one-pot synthesis of substituted carbazoles
复制标题
银-铜共催化级联分子内环化/脱亚磺酰胺/脱氢：取代咔唑的一锅法合成
DOI：
10.1039/c8cc03600d
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发表时间：
2018
影响因子：
4.9
通讯作者：
Wang Qingmin
中科院分区：
文献类型：
--
作者：
Huang Yuanqiong;Guo Zhonglin;Song Hongjian;Liu Yuxiu;Wang Qingmin
本文报道了一种银和铜共催化的级联分子内环化/双甲酰胺/脱氢反应合成取代咔唑的新方法。该反应涉及新的C-C键和C-N键的形成以及C-N键的断裂，以高产率得到多种咔唑，并显示出良好的官能团耐受性。
Herein, a silver and copper co-catalyzed cascade intramolecular cyclization/desulfinamide/dehydrogenation reaction for the synthesis of substituted carbazoles is reported. This reaction, which involved formation of new C–C and C–N bonds as well as C–N bond cleavage, afforded diverse carbazoles in high yields and showed good functional group tolerance.