Wiring electrons of cytochrome c with silver nanoparticles in layered films
Wiring electrons of cytochrome c with silver nanoparticles in layered films
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DOI：
10.1002/cphc.200300817
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发表时间：
2003-12-15
期刊：
影响因子：
2.9
通讯作者：
Matsuda, N
中科院分区：
文献类型：
--
作者：
Liu, T;Zhong, J;Matsuda, N
近年来，纳米材料由于其独特的性质已被应用于蛋白质和电极之间的ET研究特别是，我们对银纳米粒子（NPs）感兴趣，因为银具有高导电性，银纳米粒子的合成已经得到了很好的证明此外，Cotton及其同事提供的证据表明，cytc在单层镀银电极上产生了明确的电化学反应在这里，我们报道了表面组装的银纳米粒子调整了界面取向，并使细胞的异质ET形成。图1显示了表面
Recently, nanomaterials have been employed in the study of ET between proteins and electrodes due to their unique properties.[6] In particular, we are interested in silver nanoparticles (NPs) since silver has high conductivity and the synthesis of silver NPs has been well-demonstrated.[7] Moreover, Cotton and co-workers have provided evidence that cytc produces well-defined electrochemistry at monolayer-coated silver electrodes.[8] Herein, we report that surface-assembled silver nanoparticles tune the interfacial orientation and™ wire∫ the heterogeneous ET of cytc. Scheme1 shows the surface