A Critical Appraisal of RAFT-Mediated Polymerization-Induced Self-Assembly.

A Critical Appraisal of RAFT-Mediated Polymerization-Induced Self-Assembly.
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DOI:
10.1021/acs.macromol.5b02602
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发表时间:
2016-03-22
期刊:
影响因子:
5.5
通讯作者:
Armes SP
Armes SP
中科院分区:
化学1区
文献类型:
--
作者:
Canning SL;Smith GN;Armes SP

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最近,聚合诱导自组装(PISA)已被广泛认为是生产尺寸、形态和表面化学受控的嵌段共聚物纳米颗粒的稳健且有效的途径。自 2012 年以来,已经发表了该领域的几篇评论,但过去三年也发表了大量新论文。在本视角中,我们对这种方法提供的各种优点进行了批判性评估,同时也指出了其当前的一些缺点。简要强调了有前途的未来研究方向以及剩余的技术挑战和未解决的问题。
Recently, polymerization-induced self-assembly (PISA) has become widely recognized as a robust and efficient route to produce block copolymer nanoparticles of controlled size, morphology, and surface chemistry. Several reviews of this field have been published since 2012, but a substantial number of new papers have been published in the last three years. In this Perspective, we provide a critical appraisal of the various advantages offered by this approach, while also pointing out some of its current drawbacks. Promising future research directions as well as remaining technical challenges and unresolved problems are briefly highlighted.