A bidentate borane as colorimetric fluoride ion sensorElectronic supplementary information (ESI) available: electronic supplementary information (ESI) available: synthetic and analytical results, including elemental analysis, for 1 and 3 and [32-F]?[S(NMe
A bidentate borane as colorimetric fluoride ion sensorElectronic supplementary information (ESI) available: electronic supplementary information (ESI) available: synthetic and analytical results, including elemental analysis, for 1 and 3 and [32-F]?[S(NMe
复制标题
DOI：
10.1039/b403596h
复制
发表时间：
2004
期刊：
影响因子：
--
通讯作者：
S. Sol;Franois P. Gabba
中科院分区：
文献类型：
--
作者：
S. Sol;Franois P. Gabba
由10-溴-9-硫杂-10-硼蒽（1）与1，8-萘二基硼酸二甲三甲苯酯（2）反应得到的亮黄色双齿二硼烷（3）可作为比色阴离子传感器，并在THF中选择性地与氟化物络合，缔合常数大于5 × 109 M−1。
The bright yellow bidentate diborane (3), obtained by reaction of 10-bromo-9-thia-10-boraanthracene (1) with dimesityl-1,8-naphthalenediylborate (2), serves as a colorimetric anion sensor and selectively complexes fluoride with an association constant greater than 5 × 109 M−1 in THF.