( N -heterocyclic carbene)-Pd catalyzed synthesis of poly(triarylamine)s by Buchwald-Hartwig coupling of aryl chlorides
( N -heterocyclic carbene)-Pd catalyzed synthesis of poly(triarylamine)s by Buchwald-Hartwig coupling of aryl chlorides
复制标题
(N-杂环卡宾)-Pd 催化芳基氯 Buchwald-Hartwig 偶联合成聚(三芳基胺)
DOI：
10.1002/pola.26239
复制
发表时间：
2012
影响因子：
4.6
通讯作者：
Hoyos M
中科院分区：
文献类型：
--
作者：
Hoyos M
使用空气和水分稳定，市售的（n -杂环碳）-Pd配合物作为预催化剂，允许前所未有的Buchwald-Hartwig多胺化芳氯与伯胺。对聚合物端盖的不同方法也进行了评价。版权所有©2012 Wiley期刊，Inc.©2012 Wiley期刊，Inc。
The use of an air and moisture stable, commercially available (N-heterocyclic carbene)-Pd complex as precatalyst allows for the unprecedented Buchwald-Hartwig polyamination of aryl chlorides with primary amines. Different approaches for the end-capping of the polymers have also been evaluated. Copyright© 2012 Wiley Periodicals, Inc.© 2012 Wiley Periodicals, Inc.