Synthesis and Characterization of Carboxylic Acids Bearing Poly(ethylene glycol) Chains

Synthesis and Characterization of Carboxylic Acids Bearing Poly(ethylene glycol) Chains
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带有聚乙二醇链的羧酸的合成与表征

DOI:
10.1055/s-0036-1591840
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发表时间:
2018
期刊:
影响因子:
2
通讯作者:
Y. Tsuji
Y. Tsuji
中科院分区:
化学4区
文献类型:
--
作者:
M. Satou;T. Fujihara;J. Terao;Y. Tsuji

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设计合成了含三个聚乙二醇链的羧酸1a和1b和含一个聚乙二醇链的羧酸1c。通过核磁共振和电喷雾质谱(ESI-HRMS)对其结构进行了表征。在钯催化的1-苯乙醇的有氧氧化反应中,1a和1b作为羧酸配体表现良好。
Carboxylic acids1aand1bbearing three poly(ethylene glycol) (PEG) chains and carboxylic acid1cbearing one PEG chain were designed and synthesized. The carboxylic acids1a–cwere fully characterized by NMR and ESI-HRMS analyses. In a Pd-catalyzed aerobic oxidation of 1-phenylethanol,1aand1bworked well as carboxylate ligands.
DOI: 10.1021/jo048115z
发表时间: 2005-03-18
影响因子: 3.6
作者:
Taillier, C;Gille, B;Cossy, J
通讯作者: Cossy, J