TRANSITION-METAL-CATALYZED REACTIONS OF DIAZOESTERS - INSERTION INTO C-H BONDS OF PARAFFINS BY CARBENOIDS
TRANSITION-METAL-CATALYZED REACTIONS OF DIAZOESTERS - INSERTION INTO C-H BONDS OF PARAFFINS BY CARBENOIDS
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DOI：
10.1039/c39810000688
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发表时间：
1981-01-01
影响因子：
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通讯作者：
TEYSSIE, P
中科院分区：
文献类型：
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作者：
DEMONCEAU, A;NOELS, AF;TEYSSIE, P
全氟酸的羧酸铑（II）是非常有效的催化剂，用于促进卡宾（类卡宾）（由重氮酯产生）插入烷烃的C-H键中，其选择性不同于在典型的游离卡宾过程中观察到的那些。
Rhodium(II) carboxylates of perfluoroacids are very efficient catalysts for promoting the insertion of carbenes (carbenoids)(generated from diazoesters) into the C–H bonds of alkanes with selectivites which differ from those observed in typical free-crbene processes.