Modulation of the copper-dioxygen reactivity by stereochemical effect of tetradentate tripodal ligands
Modulation of the copper-dioxygen reactivity by stereochemical effect of tetradentate tripodal ligands
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DOI：
10.1246/cl.2002.416
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发表时间：
2002-03-05
影响因子：
1.6
通讯作者：
Kitagawa, T
中科院分区：
文献类型：
--
作者：
Hayashi, H;Uozumi, K;Kitagawa, T
具有空间位阻Me-3-tpa的铜（I）络合物的二氧反应性和其含氧物质对配体的单加氧酶活性通过吡啶基上的6-甲基的存在而显著调节。
Dioxygen reactivity of a copper(I) complex having a sterically hindered Me-3-tpa and monooxygenase activity of its oxygenated species toward the ligand were significantly modulated by the presence of the 6-methyl group onto pyridyl group.