Further Studies on Ni/Zr-mediated One-pot Ketone Synthesis: Use of a Mixture of NiI- and NiII-catalysts Greatly Improves the Molar Ratio of Coupling Partners

Further Studies on Ni/Zr-mediated One-pot Ketone Synthesis: Use of a Mixture of NiI- and NiII-catalysts Greatly Improves the Molar Ratio of Coupling Partners
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DOI:
10.1246/cl.190405
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发表时间:
2019-07
期刊:
影响因子:
1.6
通讯作者:
Atsushi Umehara;Y. Kishi
Atsushi Umehara;Y. Kishi
中科院分区:
化学4区
文献类型:
--
作者:
Atsushi Umehara;Y. Kishi

文献摘要

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采用(Me)3tpy·NiII-和py-(Me)酰亚胺·niiicl2 -混合催化剂,制备了一种新的Ni/ zr介导的一锅酮合成方法。Ni -催化剂选择性地激活碘化物,而Ni…
A new Ni/Zr-mediated one-pot ketone synthesis is developed, with use of a mixture of (Me)3tpy·NiII- and py-(Me)imid·NiIICl2-catalysts. The NiI-catalyst selectively activates iodides, whereas the Ni...